Gym · Equilibrium & acid–base
Weak-acid pH: solve the ICE table for [H⁺]
A weak acid only partly ionizes, so its pH is not simply −log of its concentration — you have to solve the equilibrium. Each drill gives a weak acid, its Kₐ, and how concentrated the solution is; you find the pH the real way, from the ICE table's mass-action root (the same solver the acetic-acid lesson uses). Type your answer (rounded to three significant figures). If you slip, the drill names the mistake — treating the weak acid as strong (pH = −log[HA]₀), confusing Kₐ with the hydrogen-ion concentration (that gives the pKₐ), or forgetting the square root in [H⁺] = √(Kₐ·[HA]₀). The arithmetic is machine-checked; the equilibrium model is disclosed, not proved, and Kₐ is a sourced measured value.
Model: One dominant equilibrium: only the acid's ionization matters, and water's own autoionization is neglected ([H⁺]₀ = 0). Valid when the acid's [H⁺] ≫ 10⁻⁷. Activities are approximated by molar concentrations — the ideal-dilute-solution model, which is why Kₐ is written with concentrations. The arithmetic is machine-checked and the answer is reported to 3 significant figures.
A 0.2 M solution of hydrocyanic acid (HCN) has Kₐ = 4.9×10⁻¹⁰. What is the pH? (Solve HCN ⇌ H⁺ + A⁻ for [H⁺], then pH = −log₁₀[H⁺].)
Concepts in this gym
Lessons that use this
See these skills worked in depth on a single scenario:
- The pH of a weak acid: acetic acid →
- The pH of a weak base: ammonia →
- A buffer resists change: acetic acid + acetate →
- One acid, three protons: the pH of phosphoric acid →
- How much dissolves? The solubility of calcium fluoride →
- The common-ion effect: calcium fluoride in a fluoride solution →
- Watching the pH climb: titrating acetic acid with NaOH →
- Will it precipitate? Mixing calcium and fluoride solutions →
- Insoluble, but no precipitate? Dilute magnesium and hydroxide →